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Chemical oxygen demand calculator

Calculate titrimetric COD from blank and sample FAS volumes, equivalent concentration and wastewater sample volume.

Calculator

COD (mg O2/L)
160.000000
Blank FAS volume
20
Sample FAS volume
10
FAS normality (eq/L)
0.100000
Wastewater volume
50

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How this calculator works

Use the difference in ferrous ammonium sulfate titrant between a reagent blank and digested sample. The oxygen equivalent is 8 g per equivalent. Both titrant and sample volumes must share a volume basis; the unit selectors convert them automatically. Interferences, digestion conditions and dilution corrections remain part of the laboratory method.

Formula

COD (mg O2/L) = (Vblank - Vsample) x N x 8000 / Vwastewater, with all volumes in the same unit.

Worked example

A 20 mL blank, 10 mL sample titration, 0.1 eq/L FAS and 50 mL wastewater give 160 mg O2/L. A 5 mL difference gives 80 mg O2/L.

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Frequently asked questions

What does a zero difference mean?

The uncorrected measured COD is zero; detection limits still apply.

Is COD the same as BOD?

No. COD measures oxidation under the specified chemical method; BOD measures biological oxygen use.

Where do I apply sample dilution?

Use the original-equivalent sample volume, or multiply the measured diluted-sample COD by its dilution factor.

Sources

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