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Reaction quotient calculator

Calculate Q from lists of reactant and product activities and coefficients, then compare it with an equilibrium constant to infer reaction direction.

Calculator

Reaction quotient Q
3.000000
Direction towards equilibrium
Forward: towards products
Activity terms
SideActivityCoefficient
Reactant1.0000001.000000
Reactant2.0000001.000000
Product6.0000001.000000

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How this calculator works

Enter activities and the matching positive coefficients from the balanced reaction, in the same order on each side. A solution activity is often approximated by concentration divided by a 1 mol/L reference; ideal gas activity uses partial pressure divided by a specified standard pressure. Pure solids and liquids are omitted. Q uses the current state, which need not be at equilibrium. Comparing Q and K predicts the thermodynamic direction at fixed conditions, not reaction speed.

Formula

Q = product(product activity^coefficient)/product(reactant activity^coefficient). Q < K favours forward change; Q > K favours reverse change.

Worked example

Activities 1 and 2 for two unit-coefficient reactants and 6 for the product give Q = 3. A reactant activity 2 with coefficient 2 and product activity 2 gives Q = 0.5.

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Frequently asked questions

Are activities molar concentrations?

Activities are dimensionless. In an ideal solution, divide mol/L by the 1 mol/L reference before entry.

Can a product activity be zero?

Yes, giving Q = 0. Reactant activities in the denominator must be positive.

Does Q below K mean a fast reaction?

No. It gives direction; kinetics determines how quickly equilibrium is approached.

Sources

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